The dodecatrienylnickel complex (1) absorbs 1 mol. equiv. of allene to yield the new bis-π-allyl intermediate (2); this absorbs a second mol. equiv. of allene to give eventually two isomeric dimethylene-cyclohexadecatrienes (4) and (5), or carbon monoxide to give the cyclic hydrocarbons (6) and (7) accompanied by the unsaturated ketone (8), which on hydrogenation forms (±)-muscone.
R. Baker, B. N. Blackett and R. C. Cookson, J. Chem. Soc., Chem. Commun., 1972, 802 DOI: 10.1039/C39720000802
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...