Rates of formation of mono-complexes of manganese(II) ion with 2,2′-bipyridyl, 1,10-phenanthroline and 2,6-bis(2-pyridyl)pyridine (terpy) have been measured in anhydrous methanol by the stopped-flow method between 227 and 273 K; the activation parameters are not in accord with the Eigen-Wilkins mechanism.
D. J. Benton and P. Moore, J. Chem. Soc., Chem. Commun., 1972, 717 DOI: 10.1039/C39720000717
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