SCHEDULED MAINTENANCE
Photolysis of 5-diazo[5-14C]homoadamantan-4-one in aqueous tetrahydrofuran leads to adamantane 2-carboxylic acid with only 0·9% of the label in the carboxylic group indicating that oxiren participation is insignificant in the Wolff rearrangement of this polycyclic system.
Z. Majerski and C. S. Redvanly, J. Chem. Soc., Chem. Commun., 1972, 694 DOI: 10.1039/C39720000694
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