Issue 9, 1972

A versatile synthesis of cyclic molybdenum– and tungsten–carbon σ-bonded complexes

Abstract

A simple dehalogenation takes place when dicarbonyl-(3-chloropropyldimethylarsine)-η-cyclopentadienyliodomolybdenum(II) is treated in tetrahydrofuran with sodium amalgam; the cyclic Mo–C compound so formed undergoes an hydride elimination reaction to give a cationic derivative of chelated allyldimethylarsine.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 571-572

A versatile synthesis of cyclic molybdenum– and tungsten–carbon σ-bonded complexes

K. P. Wainwright and S. B. Wild, J. Chem. Soc., Chem. Commun., 1972, 571 DOI: 10.1039/C39720000571

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements