The novel compound Cr[N(SiMe3)2]2(THF)2 has been prepared and characterised, and shown by X-ray crystal analysis to have the trans-square planar configuration; this contrasts with Cr(NO)[N(SiMe3)2]3 which has been found to possess a pseudo-tetrahedral (C3v) structure.
D. C. Bradley, M. B. Hursthouse, C. W. Newing and A. J. Welch, J. Chem. Soc., Chem. Commun., 1972, 567 DOI: 10.1039/C39720000567
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