Issue 9, 1972

Factors affecting trans/cis olefin ratios in elimination reactions of alkyl bromides

Abstract

Hindrance to free rotation of the alkyl group on Cα is used to explain abnormally high trans/cis olefin ratios and different trans/cis ratios of the same olefin formed from isomeric substrates in E2 reactions of alkyl bromides.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 561-562

Factors affecting trans/cis olefin ratios in elimination reactions of alkyl bromides

I. N. Feit and L. F. Gitlin, J. Chem. Soc., Chem. Commun., 1972, 561 DOI: 10.1039/C39720000561

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