The reaction of phosphinimines of the type RN = PPh3(R = PhCO or Ph) with rhenium and osmium oxo-complexes provides a new route to arylimido-complexes and to the previously unknown rhenium aroylimido- and osmium arylimido-complexes; a series of novel molybdenum arylimido-derivatives has been obtained from a molybdenum oxo-complex and 1,2-disubstituted hydrazines.
J. Chatt and J. R. Dilworth, J. Chem. Soc., Chem. Commun., 1972, 549 DOI: 10.1039/C39720000549
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