The sulphur–sulphur bond lengths in 2,5-dianilino-3,4-diaza-1,6,6a-trithiapentalene are 2·475(3) and 2·225(3)Å, and the difference in sulphur–sulphur bond lengths may be partly due to intermolecular N–H⋯N bonding and to the different geometries of the anilino-groups.
A. Hordvik and P. Oftedal, J. Chem. Soc., Chem. Commun., 1972, 543 DOI: 10.1039/C39720000543
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