The existence of both monomeric π-bonded dinitriles and dimeric σ-bonded dinitriles is postulated and its is suggested that the monomeric π-complexes are the kinetically favoured species, whereas the σ-bonded complexes are the thermodynamically favoured form.
M. F. Farona and K. F. Kraus, J. Chem. Soc., Chem. Commun., 1972, 513 DOI: 10.1039/C39720000513
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