SCHEDULED MAINTENANCE
Phospholium ion (1) is cleaved by sodium methoxide into 1,2,5-triphenylphosphole and acrylonitrile at a rate substantially greater than that observed for comparable phosphonium ions, a finding which is consistent with significant delocalization of the lone electron pair on phosphorus in phospholes.
W. B. Farnham and K. Mislow, J. Chem. Soc., Chem. Commun., 1972, 469 DOI: 10.1039/C39720000469
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