Self-consistent field calculations on two cyclic phosphazenes reveal that there are surprisingly large intra-ring phosphorus–phosphorus bond orders; it is suggested that these P–P bonds are important contributors to the stability of the compounds.
D. R. Armstrong, G. H. Longmuir and P. G. Perkins, J. Chem. Soc., Chem. Commun., 1972, 464 DOI: 10.1039/C39720000464
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