The reaction of WSCl4 with 1,2-dimethoxyethane (dme) results in oxygen abstraction and the formation of a complex that a single-crystal study shows may be formulated as WSCl4, WOSCl2dme; the WSCl4 and WOSCl2,dme units are linked through the oxygen atom of the WOCl2 unit, both tungsten atoms having a distorted octahedral environment.
D. Britnell, M. G. B. Drew, G. W. A. Fowles and D. A. Rice, J. Chem. Soc., Chem. Commun., 1972, 462 DOI: 10.1039/C39720000462
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...