Issue 7, 1972

Reductive cyclization of disubstituted pyridines and intramolecular aldolization of unsymmetrical diketones

Abstract

The relative proportions of alternative cyclohexenones formed on the one hand from systems of the type 2-CH2R,6-methylpyridine by reductive cleavage, and on the other hand from systems of the type Ac[CH2]3CO·CH2R by alkaline cyclization may be different and may depend on the steric requirements of R.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 374-375

Reductive cyclization of disubstituted pyridines and intramolecular aldolization of unsymmetrical diketones

S. Danishefsky, A. Nagel and D. Peterson, J. Chem. Soc., Chem. Commun., 1972, 374 DOI: 10.1039/C39720000374

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