The characterisation of the complete series of ions [PClnBr4–n]+, (0 ⩽n⩽ 4), including the previously unknown species [PCl2Br2]+ and [PBr3Cl]+, has been accomplished in the solid state using 31P n.m.r. spectroscopy.
K. B. Dillon and P. N. Gates, J. Chem. Soc., Chem. Commun., 1972, 348 DOI: 10.1039/C39720000348
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