Issue 6, 1972

Substitution vs. rearrangement in 7-chloro-7-methylbicyclo[3,2,0]hept-2-en-6-ones. The importance of C-7 stereochemistry

Abstract

The chloromethylketen adducts of cyclopentadiene undergo competitive stereospecific substitution and rearrangement reactions with nucleophilic bases which depend upon the base strength and the C-7 stereochemistry of the starting material.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 333-334

Substitution vs. rearrangement in 7-chloro-7-methylbicyclo[3,2,0]hept-2-en-6-ones. The importance of C-7 stereochemistry

D. L. Garin and K. L. Cammack, J. Chem. Soc., Chem. Commun., 1972, 333 DOI: 10.1039/C39720000333

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