Issue 4, 1972

On supposedly five-co-ordinate titanium(IV) complexes. The crystal and molecular structure of Cl3Ti(C5H7O2)

Abstract

An X-ray diffraction study shows that the titanium(IV) complex, Cl3Ti(C5H7O2), of apparent five-co-ordinate stoicheiometry is, in the solid state, a centrosymmetric chlorine-bridged dimer in which each titanium atom is six-co-ordinate and carries a bidentate acetylacetonate (C5H7O2) ligand.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 217-218

On supposedly five-co-ordinate titanium(IV) complexes. The crystal and molecular structure of Cl3Ti(C5H7O2)

N. Serpone, P. H. Bird, D. G. Bickley and D. W. Thompson, J. Chem. Soc., Chem. Commun., 1972, 217 DOI: 10.1039/C39720000217

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