Unimolecular decomposition by CH3 loss has been observed with a half-pressure for stabilization of about 75 Torr for the excited biradicals formed by the addition of triplet 3(14CH2) to both cis-and trans-but-2-ene; as much as 9% of the 14C activity is found in C8 compounds formed by radical combination reactions of 14C-labelled butenyl radicals.
D. C. Montague and F. S. Rowland, J. Chem. Soc., Chem. Commun., 1972, 193 DOI: 10.1039/C39720000193
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