The thermolysis and photolysis of the novel cyclic peroxalate (1) affords acetone and 3,3,6,6-tetramethyl-1,2-dioxan (2), and on the basis of kinetic and thermochemical studies it is shown that multiple bond fragmentation in (1) is inhibited due to conformational effects.
W. Adam and J. Sanabia, J. Chem. Soc., Chem. Commun., 1972, 174 DOI: 10.1039/C39720000174
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