The mechanism of formation of propionaldehyde and π-allylplatinum(II) complexes from allyl alcohol and diallyl ether with cationic platinum(II) hydrides
Abstract
Migration of the C
C bond and chelate ring formation occur in the insertion reactions of allylic acetates with cationic platinum(II) hydrides; similar behaviour explains the formation of π-allylplatinum(II) complexes and propionaldehyde from reactions of allyl alcohol or diallyl ether with such cationic hydrides.
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