Issue 3, 1972

The mechanism of formation of propionaldehyde and π-allylplatinum(II) complexes from allyl alcohol and diallyl ether with cationic platinum(II) hydrides

Abstract

Migration of the C[double bond, length half m-dash]C bond and chelate ring formation occur in the insertion reactions of allylic acetates with cationic platinum(II) hydrides; similar behaviour explains the formation of π-allylplatinum(II) complexes and propionaldehyde from reactions of allyl alcohol or diallyl ether with such cationic hydrides.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 150-151

The mechanism of formation of propionaldehyde and π-allylplatinum(II) complexes from allyl alcohol and diallyl ether with cationic platinum(II) hydrides

H. C. Clark and H. Kurosawa, J. Chem. Soc., Chem. Commun., 1972, 150 DOI: 10.1039/C39720000150

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