Empirical relationships have been derived for the variation of Jgem with respect to the orientation of the lone pairs on the adjacent oxygen and sulphur atoms; a similar relationship has been obtained for a sulphone group but a different one for a sulphoxide group.
R. Davies and J. Hudec, J. Chem. Soc., Chem. Commun., 1972, 124 DOI: 10.1039/C39720000124
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