X-Ray analysis demonstrates that the “V” amylose helix is left-handed, that oxygen(6) is in a gauche–trans conformation in “V” amylose dehydrate, and that the helix undergoes a net 30° rotation upon hydration.
A. French and B. Zaslow, J. Chem. Soc., Chem. Commun., 1972, 41 DOI: 10.1039/C39720000041
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