A preliminary rate study of the reaction of potassium ferrate(VI) with several substituted benzyl alcohols has shown that electron-withdrawing substituents increase the rate of reaction and as well result in the largest intramolecular hydrogen–deuterium isotope effects; the results are discussed in terms of a suggested mechanism for the oxidation process.
R. J. Audette, J. W. Quail and P. J. Smith, J. Chem. Soc., Chem. Commun., 1972, 38 DOI: 10.1039/C39720000038
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