In solutions of low conductivity, the current at a rotating disc electrode may not be uniform. A simplified but more approximate version of Newman's theory 1 is presented, together with a diagnostic diagram for whether the effect will be important or not in any particular experiment.
W. J. Albery and M. L. Hitchman, Trans. Faraday Soc., 1971, 67, 2408 DOI: 10.1039/TF9716702408
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