A simple technique for the measurement of rates of deactivation of N2A3Σ+u

A. B. Callear; P. M. Wood

doi:10.1039/TF9716700598

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A simple technique for the measurement of rates of deactivation of N₂A³Σ ⁺_u

A. B. Callear and P. M. Wood

Abstract

By subjecting gas mixtures containing NO, at low pressures, and N₂ to a short duration flash of ultra-violet radiation, it was demonstrated from the delayed NOγ-emission that N₂A³Σ⁺_u is produced in the quenching of NOC²Π(v= 0) by N₂. The rate coefficient for removal of N₂A³Σ⁺_u by H₂O was recorded as 5.5 (±3.0)× 10^–14 cm³ molecule^–1 s^–1.

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DOI: https://doi.org/10.1039/TF9716700598
Article type: Paper

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Trans. Faraday Soc., 1971,67, 598-600

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A simple technique for the measurement of rates of deactivation of N₂A³Σ⁺_u

A. B. Callear and P. M. Wood, Trans. Faraday Soc., 1971, 67, 598 DOI: 10.1039/TF9716700598

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Transactions of the Faraday Society