Volume 67, 1971

Study of fast reactions in solution using a dielectric-heating relaxation technique

Abstract

A microwave-pulse temperature-jump relaxation technique is described. Temperature rises of about 0.5 K may be produced in non-polar solvent media in about 1 µs. Spectrophotometric detection is used to monitor the resulting chemical relaxation. A conductimetric detection system is also described and applied to the measurement of relaxation times in the millisecond range in an aqueous solution.

Article information

Article type
Paper

Trans. Faraday Soc., 1971,67, 97-103

Study of fast reactions in solution using a dielectric-heating relaxation technique

K. J. Ivin, J. J. McGarvey and E. L. Simmons, Trans. Faraday Soc., 1971, 67, 97 DOI: 10.1039/TF9716700097

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