Issue 0, 1971
From the journal:

Journal of the Chemical Society C: Organic

Re-examination of the vinyl chloride–phosphorus trichloride–oxygen reaction: an example of direct formation of a phosphate derivative from an olefin

C. B. C. Boyce  and  Shirley B. Webb  

Abstract

Contrary to previous reports, the reaction of vinyl chloride with phosphorus trichloride and oxygen gives as the main products a 1·7 : 1 mixture of Cl2P(:O)·O·CHCl·CH2Cl and Cl2P(:O)·CHCl·CH2Cl; the former has been incorrectly assigned the structure Cl2P(:O)·CH2·CHCl2.

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Article information

DOI
https://doi.org/10.1039/J39710003987
Article type
Paper

J. Chem. Soc. C, 1971, 3987-3990

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Re-examination of the vinyl chloride–phosphorus trichloride–oxygen reaction: an example of direct formation of a phosphate derivative from an olefin

C. B. C. Boyce and S. B. Webb, J. Chem. Soc. C, 1971, 3987 DOI: 10.1039/J39710003987

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