Stereospecific total syntheses of two ketones, (±)-fukinone (3) and (+)-hydroxyeremophilone (1), members of the non-isoprenoid eremophilane family of bicyclic sesquiterpenes, are described. The former synthesis begins with a cyclohexanone, which is annelated, and the latter with a bicyclic ketone of known absolute configuration.
A. R. Pinder and A. K. Torrence, J. Chem. Soc. C, 1971, 3410 DOI: 10.1039/J39710003410
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