Issue 0, 1971

The synthesis of neoclovene

Abstract

Neoclovene, a product from acid-catalysed rearrangement of caryophyllene, has been synthesised in such a manner as to demonstrate the probable intermediacy of a specific carbonium ion derived from (4S,7R)-3,3,7,11-tetramethyltricyclo[5,4,0,01,4]undecan-11-ol (24) in the formation of neoclovene from caryophyllene. This work also provides additional support for the relative configuration assigned to neoclovene.

Article information

Article type
Paper

J. Chem. Soc. C, 1971, 3375-3384

The synthesis of neoclovene

T. F. W. McKillop, J. Martin, W. Parker, J. S. Roberts and J. R. Stevenson, J. Chem. Soc. C, 1971, 3375 DOI: 10.1039/J39710003375

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