The reaction of cycloheptatriene with acyl halides in the presence of a Lewis acid does not involve a hydride-atom transfer. The reaction has been used to prepare two series of compounds, (a) benzyl ketones, and (b) 1-acylcycloheptatrienes. An intermediate common to both reactions has been identified, allowing a coherent mechanism to be postulated.
J. A. Blair and C. J. Tate, J. Chem. Soc. C, 1971, 1592 DOI: 10.1039/J39710001592
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