Chemical evidence is presented which largely establishes the constitution of fusicoccin and of its aglycone. The preparation of a suitable heavy-atom derivative has enabled the complete structure of the aglycone to be determined by X-ray crystallography. Combining this result with chemical evidence has afforded the complete structure of fusicoccin.
K. D. Barrow, D. H. R. Barton, E. Chain, U. F. W. Ohnsorge and R. Thomas, J. Chem. Soc. C, 1971, 1265 DOI: 10.1039/J39710001265
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