SCHEDULED MAINTENANCE
para-Substituted benzylidenetriarylarsoranes with para-substituted benzaldehydes give olefins when the benzylidene para-substituent is strongly electron attractive otherwise epoxides are formed. Methylenetriphenyl-arsorane with αβ-unsaturated ketones gives cyclopropanes and benzylidenetriphenylarsorane with Schiff's bases gives aziridines. Reactions of arsoranes with dimethyl acetylenedicarboxylate, phenylsulphine, and phenylsulphene are also described.
S. Trippett and M. A. Walker, J. Chem. Soc. C, 1971, 1114 DOI: 10.1039/J39710001114
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...