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Issue 0, 1971
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Some reactions of arsenic ylides


para-Substituted benzylidenetriarylarsoranes with para-substituted benzaldehydes give olefins when the benzylidene para-substituent is strongly electron attractive otherwise epoxides are formed. Methylenetriphenyl-arsorane with αβ-unsaturated ketones gives cyclopropanes and benzylidenetriphenylarsorane with Schiff's bases gives aziridines. Reactions of arsoranes with dimethyl acetylenedicarboxylate, phenylsulphine, and phenylsulphene are also described.

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Article type: Paper
DOI: 10.1039/J39710001114
J. Chem. Soc. C, 1971, 1114-1117

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    Some reactions of arsenic ylides

    S. Trippett and M. A. Walker, J. Chem. Soc. C, 1971, 1114
    DOI: 10.1039/J39710001114

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