Issue 0, 1971
From the journal:

Journal of the Chemical Society B: Physical Organic

Substituent effects on circular dichroism of α-phenylethylamines

G. Gottarelli  and  B. Samorì  

Abstract

The effect of para-substitution on the circular dichroism of α-phenylethylamine in different solvents, at room and at low temperature, has been studied. An analysis of various data and the different sensitivity of the 1∠b and 1∠a bands to changes in the pH led to the conclusion that the optical activity of the two bands is caused by different mechanisms.

A vibronic analysis of the 1∠b band which emphasises the role of non-totally symmetric vibrations is given.

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Article information

DOI
https://doi.org/10.1039/J29710002418
Article type
Paper

J. Chem. Soc. B, 1971, 2418-2423

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Substituent effects on circular dichroism of α-phenylethylamines

G. Gottarelli and B. Samorì, J. Chem. Soc. B, 1971, 2418 DOI: 10.1039/J29710002418

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