A novel extension of the Bond Energy–Bond Order method is reported, which allows the calculation of rate parameters for reactions involving the bimolecular transfer of halogen atoms. The agreement of the results with existing experimental data for reactions involving two carbon-centred radicals is discussed and the applicability of the results to organic reaction mechanisms is pointed out.
C. M. Previtali and J. C. Scainao, J. Chem. Soc. B, 1971, 2317 DOI: 10.1039/J29710002317
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