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Issue 0, 1971
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The stereochemistry of organometallic compounds. Part XI. The variable temperature nuclear magnetic resonance spectra of di-µ-chloro-bis-[(α,1,2-trihapto-3,3,5,5-tetramethylmethylenecyclohexane)-palladium(II)]

Abstract

The synthesis and variable-temperature n.m.r. spectra of di-µ-chloro-bis-[(α,1,2-trihapto-3,3,5,5-tetramethylmethylenecyclohexane)palladium(II)] are described. The spectra give convincing evidence for the σπ mechanism of exchange in dynamic π-allylic palladium systems and illustrate the general utility of 3,3,5,5-tetramethylmethylenecyclohexane as a ligand for the investigation of the dynamic stereochemistry of olefin and π-allylic metal systems.

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J. Chem. Soc. B, 1971, 2241-2243
Article type
Paper

The stereochemistry of organometallic compounds. Part XI. The variable temperature nuclear magnetic resonance spectra of di-µ-chloro-bis-[(α,1,2-trihapto-3,3,5,5-tetramethylmethylenecyclohexane)-palladium(II)]

C. W. Alexander, W. R. Jackson and W. B. Jennings, J. Chem. Soc. B, 1971, 2241
DOI: 10.1039/J29710002241

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