The addition of keten to acetic acid to give acetic anhydride is a homogeneous bimolecular gas-phase reaction between 106 and 215°C. The reaction is first-order in keten and in acid monomer and k= 105·81 exp (–46,260/-RT) l mol–1 s–1.
P. G. Blake and H. H. Davies, J. Chem. Soc. B, 1971, 1727 DOI: 10.1039/J29710001727
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