The inversion of sucrose has been carried out in hydrochloric (1—8·5M), sulphuric (1—9M), perchloric (1—7M), and phosphoric (1—11M) acids at 0·5 °C and 25·0 °C. Analysis of the rate data by use of the linear free energy relationship of Bunnett and Olsen has enabled the value of log k2°, the rate constant at infinite dilution in water, to be determined and this varies little with solvent acid.
J. W. Barnett and J. O'Connor, J. Chem. Soc. B, 1971, 1163 DOI: 10.1039/J29710001163
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