Issue 0, 1971

Evidence for adsorption as the first step in the solid-state oxidation of benzenehexol with active manganese dioxide

Abstract

Oxidation of benzenehexol on the surface of amorphous, precipitated (‘active’) manganese dioxide proceeds by a concerted mechanism, involving ionic and free-radical pathways, to give a croconic acid derivative. This manganese dioxide has a polycrystalline chain structure, in contrast to the crystalline oxidant prepared in deuterium oxide.

Article information

Article type
Paper

J. Chem. Soc. B, 1971, 889-894

Evidence for adsorption as the first step in the solid-state oxidation of benzenehexol with active manganese dioxide

A. J. Fatiadi, J. Chem. Soc. B, 1971, 889 DOI: 10.1039/J29710000889

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