Rate coefficients have been determined for the acid-catalysed methanolysis of 1,1-diphenylethylene oxide at –64, –54, and –44°, and the value of the entropy of activation (ΔS‡), –0·6 cal mol–1 K–1, is interpreted as indicating the occurrence of an A1 mechanism or a borderline A1 mechanism. The reaction was followed by g.l.c.
J. Biggs, N. B. Chapman and V. Wray, J. Chem. Soc. B, 1971, 63 DOI: 10.1039/J29710000063
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