Issue 0, 1971
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Reactions of low-valent metal complexes with fluorocarbons. Part XIX. Bis(t-butyl isocyanide)palladium and tetrakis(trimethyl phosphite or dimethylphenylarsine)palladium

H. D. Empsall,   M. Green,   S. K. Shakshooki  and  F. G. A. Stone  

Abstract

Reaction between Pd(ButNC)2 and CF2:CFX (X = Cl or Br) affords (ButNC)2Pd(CF:CF2)X. Similarly, Pd(AsMe2Ph)4 yields (PhMe2As)2Pd(CF:CF2)Cl with chlorotrifluoroethylene. Hexafluoropropene reacts with Pd(ButNC)2 to form unstable (ButNC)2[graphic omitted]F·CF3; whereas (CF3)2C:C(CN)2 gives stable (ButNC)2[graphic omitted](CN)2. Corresponding reactions with PdL4[L = AsMe2Ph or P(OMe)3] give L2[graphic omitted](CN)2. Trimethyl phosphite is displaced from the latter compound by PMePh2, PEt3, and (Ph2PCH2)2 to form the respective L2[graphic omitted](CN)2 complexes. Hexafluoro-acetone and -isopropylideneamine react with Pd(ButNC)2 to form (ButNC)2[graphic omitted] (X = O or NH). Similarly, Pd(AsMe2Ph)4 reacts with (CF3)2C:NH to form (PhMe2As)2[graphic omitted]H, whereas Pd(PPh3)4 gives (Ph3P)2[graphic omitted]H.

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Article information

DOI
https://doi.org/10.1039/J19710003472
Article type
Paper

J. Chem. Soc. A, 1971, 3472-3476

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Reactions of low-valent metal complexes with fluorocarbons. Part XIX. Bis(t-butyl isocyanide)palladium and tetrakis(trimethyl phosphite or dimethylphenylarsine)palladium

H. D. Empsall, M. Green, S. K. Shakshooki and F. G. A. Stone, J. Chem. Soc. A, 1971, 3472 DOI: 10.1039/J19710003472

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