The σ-but-3-enyl derivatives (π-C5H5)Fe(CO)2(σ-CH2·CR2·CH![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CH2), (R = H or Me) have been prepared. Irradiation of the compound where R = Me gives the heterocyclic compound (π-C5H5)(CO)[graphic omitted]CH2. The metal–ligand bonding in this compound is discussed. The but-3-enyl compounds decompose thermally giving the cyclic acyl derivatives (π-C5H5)(CO)[graphic omitted]CH2.
M. L. H. Green and M. J. Smith, J. Chem. Soc. A, 1971, 3220 DOI: 10.1039/J19710003220
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