SCHEDULED MAINTENANCE
Convenient syntheses of the complexes trans- and cis-[MCl2(HPPh2)4](M = Ru or Os) and cis-[ReCl2(PPh2)-(HPPh2)3], and of salts of the [Rh(HPPh2)4]+, [Ir(CO)(HPPh2)4]+, [RuH(HPPh2)5]+, and trans-[RuH(CO)(HPPh2)4]+ cations are described. The structures and properties of these complexes, including the formation of cis-[OsH2(HPPh2)4], are discussed.
J. R. Sanders, J. Chem. Soc. A, 1971, 2991 DOI: 10.1039/J19710002991
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