Analysis of effective potential functions for the 3d orbitals of sulphur and oxygen, obtained from atomic selfconsistent field calculations, indicate a possible origin for the non-expansion of the octet amongst first-row atoms of the Periodic Table.
R. F. Stewart and B. C. Webster, J. Chem. Soc. A, 1971, 2987 DOI: 10.1039/J19710002987
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