Issue 0, 1971
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Some oxo-complexes of molybdenum(IV) and (V) with 1,2-bisdiphenylphosphinoethane

A. V. Butcher  and  J. Chatt  

Abstract

Complexes formulated [{MoOCl3(diphos)}](red and brown isomers), MoOCl2(diphos), [MoOCl(diphos)2]+, and [MoOCl2(thf)(diphos)](diphos = Ph2P·CH2·CH2·PPh2, thf = tetrahydrofuran) have been prepared and their structures assigned on the basis of analysis, i.r. and 1H n.m.r. spectra, conductivity, and magnetic measurements. Only [MoOCl(diphos)2]+ forms alkoxy-complexes, [MoO(OR)(diphos)2]+, with alcohols in the presence of sodium carbonate.

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Article information

DOI
https://doi.org/10.1039/J19710002356
Article type
Paper

J. Chem. Soc. A, 1971, 2356-2358

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Some oxo-complexes of molybdenum(IV) and (V) with 1,2-bisdiphenylphosphinoethane

A. V. Butcher and J. Chatt, J. Chem. Soc. A, 1971, 2356 DOI: 10.1039/J19710002356

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