Issue 0, 1971
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Transition metal complexes as ligands: preparation of mixed-transition-metal complexes of molybdenum or tungsten and nickel, palladium, platinum, or rhodium

A. R. Dias  and  M. L. H. Green  

Abstract

The complexes (π-C5H5)2M(SMe)2(M = Mo or W) act as bidentate, four-electron ligands and form diamagnetic complexes of stoicheiometries [{(π-C5H5)2M(SMe)2}2M′]2+X2–(M′= Ni, Pd, or Pt), (π-C5H5)2M(SMe)2M″Cl2(M″= Pd or Pt), and [(π-C5H5)2M(SMe)2RhL2]+PF6–[L2=(CO)2, cyclo-octa-1,5-diene or (π-allyl)2]. Some of the complexes show temperature-variable 1H n.m.r. spectra which are discussed.

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Article information

DOI
https://doi.org/10.1039/J19710001951
Article type
Paper

J. Chem. Soc. A, 1971, 1951-1956

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Transition metal complexes as ligands: preparation of mixed-transition-metal complexes of molybdenum or tungsten and nickel, palladium, platinum, or rhodium

A. R. Dias and M. L. H. Green, J. Chem. Soc. A, 1971, 1951 DOI: 10.1039/J19710001951

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