The 121Sb Mössbauer spectra of a number of chloroantimony salts have been examined. The presence of both SbIII and SbV in Rb2SbCl6 is confirmed. Extremely large, negative isomer shifts are obtained for [SbIIICl6]3– species and are interpreted in terms of a stereochemically inactive Ione-pair of electrons.
T. Birchall, B. D. Valle, E. Martineau and J. B. Milne, J. Chem. Soc. A, 1971, 1855 DOI: 10.1039/J19710001855
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