The photochemical reactions of the Group VI metal hexacarbonyls with the acetylide ion, C≡CR– where the metal is Cr, Mo, or W, and R is Me or Ph are described. The bonding in these complexes is discussed and their reactions with triphenylphosphine are described.
W. J. Schlientz and J. K. Ruff, J. Chem. Soc. A, 1971, 1139 DOI: 10.1039/J19710001139
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