The preparation and properties of the complexes trans-NiMeX(PPri3)2(I), where X = Cl, Br, or l, and NiMe2(Ph2P·CH2·CH2·PPh2)(II) are described. The complexes (I) react with triphenylphosphine to give the complexes NiX(PPh3)3, X = Cl, Br, or l, and NiMel(PPri3)2 reacts with methyl iodide to give [PPri3Me][Nil3PPri3]. Complex (II) reacts with phenol to give the phenoxy-derivative Ni(Ph2P·CH2·CH2·PPh2)Me(OPh).
M. L. H. Green and M. J. Smith, J. Chem. Soc. A, 1971, 639 DOI: 10.1039/J19710000639
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