Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 21st October 2020 from 07:00 AM to 07:00 PM (BST).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 0, 1971
Previous Article Next Article

Zerovalent platinum chemistry. Part V. Bistriphenylphosphineplatinum(0) quinone complexes

Abstract

Compounds of formula [Pt(PPh3)2(quinone)] where the quinone is 1,4-benzoquinone, 2,3,5,6-tetrachloro-1,4-benzoquinone-1,4-naphthoquinone, 3,4,5,6-tetrachloro-1,2-benzoquinone, 1,2-naphthoquinone, and 9,10-phenanthrenequinone have been synthetised. With 2,3,5,6-tetramethyl-1,4-benzoquinone a compound of formula {Pt(PPh3)2}2(quinone) has been obtained. The type of bonding and the factors influencing the strength of the bond between Pt(PPh3)2 and the quinone moiety have been discussed on the basis of i.r., 1H n.m.r. and electronic spectra.

Back to tab navigation

Article information


J. Chem. Soc. A, 1971, 416-422
Article type
Paper

Zerovalent platinum chemistry. Part V. Bistriphenylphosphineplatinum(0) quinone complexes

S. Cenini, R. Ugo and G. La Monica, J. Chem. Soc. A, 1971, 416
DOI: 10.1039/J19710000416

Search articles by author

Spotlight

Advertisements