Issue 18, 1971

1,1,2-Trimethylpropyldialkylcyanoborates as intermediates for the synthesis of symmetrical, unsymmetrical, functionalised, and cyclic ketones

Abstract

The insertion reaction of cyanide into thexyldialkylcyanoborates, using acylation at low temperatures followed by oxidation, provides the mildest known method for the high-yield production of ketones from olefins via organoboranes.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 1048b-1050

1,1,2-Trimethylpropyldialkylcyanoborates as intermediates for the synthesis of symmetrical, unsymmetrical, functionalised, and cyclic ketones

A. Pelter, M. G. Hutchings and K. Smith, J. Chem. Soc. D, 1971, 1048b DOI: 10.1039/C2971001048B

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