Mesitylenesulphonyl (‘mesisyl’) chloride has been shown to react with vic-hydroxy-systems to give the mono-ester as the major or sole product, and an improved procedure for the synthesis of methyl 2,3-anhydro-4,6-O-benzylidene-α-D-mannoside is given; vic-di-O-mesisyl esters are not cleaved by alkali to give epoxides.
S. E. Creasey and R. D. Guthrie, J. Chem. Soc. D, 1971, 801b DOI: 10.1039/C2971000801B
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...